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Saturday, 06 August 2011 03:22

Amines, Aliphatic: Physical & Chemical Properties

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Chemical Name

CAS-Number

Colour/Form

Boiling Point (ºC)

Melting Point (ºC)

Molecular Weight

Solubility in Water

Relative Density (water=1)

Relative Vapour Density (air=1)

Vapour Pressure/ (Kpa)

Inflam.
Limits

Flash Point (ºC)

Auto Ignition Point (ºC)

ACETALDEHYDE-OXIME
107-29-9

needles; two crystalline modifications

115

47

59.07

sol

0.9656

@ 25.8 ºC

<22

ALLYLAMINE
107-11-9

colourless to light yellow liquid

55-58

-88

57.09

misc

0.76

2.0

26.4

2.2 ll
22 ul

-29 cc

370

BUTYLAMINE
109-73-9

clear, colourless liquid

77.8

-50

73.1

misc

0.7414

2.5

10.9

1.7 ll
9.80 ul

-1 oc

312

sec-BUTYLAMINE
13952-84-6

colourless liquid

63

-104

73.14

misc

0.724

2.52

18

1.7 ll
9.8 ul

- 9

378

tert-BUTYLAMINE
75-64-9

colourless liquid

44

-72.65

73.1

misc

0.6951

2.5

@ 25 ºC.

1.7 ll
8.9 ul

10

380

CYCLOHEXYLAMINE
108-91-8

colourless to yellow liquid

134

-17.7

99.17

sol

0.8191

3.42

1.2

1.5 ll
9.4 ul

31 cc

293

DIALLYLAMINE
124-02-7

liquid

111

-88.4

97.2

8.6 g/ 100 ml

@ 10 ºC/4 ºC

3.35

2.4

21

1,3-BUTANEDIAMINE
590-88-5

water white liquid

143-150

0.858

516

1,5-PENTANEDIAMINE
462-94-2

179

9

102.17

sol

0.873 25 ºC

1,3-PROPANEDIAMINE
109-76-2

140

74.12

sol

0.884

DIBUTYLAMINE
111-92-2

liquid; colourless

160

-60-59

129.24

sol

0.7670

4.46

1.9 mm Hg

1.1

57 oc

2,2'-DICHLORO-N-­METHYLDIETHYLAMINE
51-75-2

mobile liquid

@ 18 mm Hg

-60

156.07

sl sol

@ 25 ºC/4 ºC

DICYCLOHEXYLAMINE
101-83-7

colourless liquid

256

-0.1

181.31

sl sol

0.9123

6.25

110

DIETHANOLAMINE
111-42-2

prisms; usually offered as a viscous liquid; crystalline solid

268.8

28

105.1

v sol

1.0966

3.65

< 0.001

134 oc

660

DIETHYLAMINE
109-89-7

colourless liquid

55.5

-49.8

73.1

v sol

0.71

2.53

25.9

1.8 ll
10.1. ul

-26 cc

312

2-DIETHYLAMINO­ETHANOL
100-37-8

colourless liquid

163

-70

117.19

misc

0.8921

4.03

0.19

6.7 ll
11.7 ul

52 cc

250

DIETHYLENETRIAMINE
111-40-0

yellow liquid

207

-39

103.2

misc

0.96

3.56

0.037

1 ll
10 ul

97-102 oc

390-395

DIISOPROPYLAMINE
108-18-9

colourless liquid

84

-61

101.19

sl sol

0.7169

3.5

8.0

0.8 ll
7.1 ul

-1 oc

316

DIMETHYLAMINE
124-40-3

gas at ordinary temperature; colourless gas

7

-92

45.08

v sol

0.680

1.6

206

2.8 ll
14.4 ul

402

DIMETHYLAMINE HYDROCHLORIDE
506-59-2

171

81.54

v sol

3-DIMETHYLAMINO­PROPYLAMINE
109-55-7

colourless liquid

123

-70

102.2

sol

@ 30 ºC

3.5

DIMETHYLETHANOL­AMINE
108-01-0

colourless liquid

135

-59

89.1

misc

0.8866

3.03

560

41oc

220

3,3'-DIAMINODIPRO­PYLAMINE
56-18-8

@ 50 ºC

-14

131.22

@ 25 ºC

ETHANOLAMINE
141-43-5

viscous, clear, hydroscopic fluid; viscous liquid

171

10.5

61.08

misc

1.0180

2.1

@ 25 ºC

85 cc

410

ETHYLAMINE
75-04-7

colourless liquid or gas

17

-81

45.08

misc

@ 15 ºC/15 ºC

1.55

121

3.5 ll
14 ul

-17 cc

725

ETHYLENEDIAMINE
107-15-3

colourless liquid; water-white liquid

117

8.5

60.10

v sol

0.8979

2.07

1.2

4.2 ll
14.4 ul

34 cc

385

ETHYLENIMINE
151-56-4

colourless, mobile fluid; oil

56-57

-71.5

43.08

sol

@ 24 ºC/4 ºC

1.48

21.3

3.6 ll
46 ul

11 cc

322

2-ETHYLHEXYLAMINE
104-75-6

colourless liquid

129.24

sol

1.2

60 oc

HEXAMETHYLENE­DIAMINE
124-09-4

colourless leaflets; rhombic bipyramidal plates

205

42

116.20

v sol

0.93

4.01

@ 50 ºC

0.7 ll
6.3 ul

71

310

HYDROXYETHYL ETHYLENEDIAMINE
111-41-1

colourless liquid

238-40

104.15

misc

1.0286

3.59

@ 25 ºC

135 cc

ISOBUTANOLAMINE
124-68-5

crystalline mass

165

31

89.1

misc

0.934

3.0

67 cc

ISOBUTYLAMINE
78-81-9

colourless liquid

68

-85

73.1

v sol

@ 25 ºC/4 ºC

2.5

@ 18.8 ºC

3.4 ll
9 ul

378

ISOPHORONE DIAMINE
2855-13-2

colourless liquid

247

10

170.30

v sol

0.92

2 Pa

110

ISOPROPANOLAMINE
78-96-6

liquid

159.46

1.74

75.11

sol

0.9611

2.6

< 0.2

77

374

ISOPROPYLAMINE
75-31-0

colourless liquid

33-34

-101

59.1

misc

@ 15 ºC/4 ºC

2.04

@ 25 ºC

2.3 ll
12 ul

-37 oc

402

HEXAMETHYLENE­TETRAMINE
100-97-0

rhombic crystals from alcohol; crystals or granules or powder; colourless, lustrous crystals or white crystalline powder

140.19

1 g /1.5 ml

@ -5 ºC

ETHYL METHYL KETONE OXIME
96-29-7

152.5

-29.5

87.12

sol

0.9232

METHYLAMINE
74-89-5

colourless gas or liquid

-6.3

-94

31.1

v sol

0.6628

1.07

290

4.9 ll
20.7 ul

430

2-METHYLAMINO­ETHANOL
109-83-1

viscous liquid

155-156

-4.5

75.11

misc

0.937

2.6

0.7 mm Hg

74 oc

2-DIBUTYLAMINO­ETHANOL
102-81-8

colourless liquid

224-232

173.29

0.859

933

DIISOPROPANOLAMINE
110-97-4

crystals

@ 745 mm Hg

44.5

133.2

sol

0.989

4.6

@ 42 ºC

1.1 ll
5.4 ul

127

374

DIPENTYLAMINE
2050-92-2

colourless to light-yellow liquid

202

-44

157.3

sl sol

0.7771

5.4

52

PROPYLAMINE
107-10-8

colourless liquid

48-49

-83

59.11

sol

0.72

2.0

33.1

2.0 ll
10.4 ul

<-37 oc

317

PROPYLENEDIAMINE
78-90-0

119.5

74.12

v sol

@ 15 ºC

TETRAETHYLENE­PENTAMINE
112-57-2

viscous, hygroscopic liquid; yellow liquid

340

-30

189.3

sol

0.9980

6.53

@ 25 ºC

163 oc

321

TRIALLYLAMINE
102-70-5

liquid

155.5

-70

137.2

0.25 g/100 ml

0.809

4.73

39 oc

TRIBUTYLAMINE
102-82-9

colourless liquid; pale yellow liquid

216.5

-70

185.34

sl sol

0.78

6.39

@ 25 ºC

86 oc

TRIETHANOLAMINE
102-71-6

viscous liquid; colourless to pale yellow

335

20.5

149.2

misc

1.1242

5.1

< 0.01 mm Hg

TRIETHYLAMINE
121-44-8

colourless liquid

89

-115

101.19

sol

0.7275

3.49

@ 31.5 ºC

1.2 ll
8.0 ul

-667 oc

TRIETHYLENETETRAMINE
112-24-3

moderately viscous, yellowish liquid

266.5

12

146.2

v sol

0.9818

5.04

1.3 Pa

1.1 ll
>6.4 ul

118-143 cc

338

TRIISOPROPANOLAMINE
122-20-3

crystals

305

45

191.3

sol

1.0

<0.001

160

320

TRIMETHYLAMINE
75-50-3

colourless gas

3

-117

59.11

v sol

0.6356

2.0

220

2.0 ll
11.6 ul

12 cc

190

TRIPROPYLAMINE
102-69-2

water white liquid

150-156

-94

143.28

0.7558

405

 

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Contents

Preface
Part I. The Body
Part II. Health Care
Part III. Management & Policy
Part IV. Tools and Approaches
Part V. Psychosocial and Organizational Factors
Part VI. General Hazards
Part VII. The Environment
Part VIII. Accidents and Safety Management
Part IX. Chemicals
Part X. Industries Based on Biological Resources
Part XI. Industries Based on Natural Resources
Part XII. Chemical Industries
Part XIII. Manufacturing Industries
Part XIV. Textile and Apparel Industries
Part XV. Transport Industries
Part XVI. Construction
Part XVII. Services and Trade
Part XVIII. Guides